Caesar wears a big light blue colored coat with "GAS" printed in pink on each side (in his first appearances this was not present). Under his coat, he wears a pair of diagonally striped yellow overalls which are striped cross with orange lines. The overall is cut off right under his knees, exposing his hairy legs. He also wears dark purple gloves with the initials "CC" in white on them.[8] Due his constant gaseous form, he seems to not use shoes, remaining barefoot, though only when his powers were disabled, his feet solidified with the rest of his body along with a simple pair of shoes. Four years before his debut, Caesar had shorter hair that was more rounded, and wore a polka dot patterned shirt beneath his coat. During his third fight with Luffy, Luffy greatly damaged Caesar's face, which knocked some of his teeth out and bent his facial structure inwards, and seemingly breaking his nose. As result, his pronunciation became a bit hard to understand. After absorbing the Shinokuni, Caesar's entire body structure changed to a darker gas color matching that of the gas, becoming as comparably large as a giant, with his hair growing completely wild and overly long. He also grows a coral-shaped crown behind his horns. The word in kanji "Land of Death" is written on the front of his chest. Upon his defeat, he returns to normal. In the anime, Caesar's skin tone is shown to be a pale white, while in the manga it is shown as a more natural tone. Caesar is, in Smoker's words, "one very crazy bastard", and his actions on Punk Hazard validate the Marine vice-admiral's claim. A very cruel, arrogant, scheming, sinister, and overall a very evil person, Caesar takes great delight in causing harm and destruction to anything and anybody around him. His psychopathic nature is displayed many times, such as when he set off a chemical weapon on Punk Hazard, killing or crippling most of its inhabitants and destroying its environment, selling or creating weapons of mass destruction for similarly unscrupulous individuals such as Doflamingo, performing sick experiments on children and drugging them with a lethal, addictive drug to ensure that they do not run away, and trying to murder everyone on Punk Hazard (Trafalgar Law, the Straw Hats, Smoker's Marines, the children, and his own blindly following, minions) so he could test out his new poisonous gas weapon-pet, Smiley – all of which he does without a shred of remorse or empathy for his potential victims.
He appears to have a grudge against Vegapunk, as well as a cautious disposition, as shown when he hid from the Marines instead of trying to engage them immediately, as well as trusting Monet's deduction that the Straw Hats might be more powerful than their bounties claim, and waiting for Joker's approval to make his actions look like accidents, before starting attacks. Caesar is also a rather economizing person, as he did not want to waste the poison by clearing it off, but rather, collected, saved and compressed it into Smiley. He also appears to be able to act or lie on several occasions, often being seen feigning emotions when lying to his subordinates and to the children, a trait that was quickly noted by Monet when he attempted to show false concern for his subordinates facing Smiley. However, with the blind trust of his subordinates and some crocodile tears, he was able to deceive them easily, leading them to believe that Vegapunk was responsible for the Punk Hazard explosion four years ago. Caesar also is very ill-tempered and quick to anger when things do not go his way, such as yelling at his subordinates to let the gas come in to kill the intruders and his own men and again when Monet pointed out that Vergo would die and Caesar just yelled, unconcerned about his potential disloyalty. Upon losing the upper hand against Luffy during their last fight, Caesar lost his composure and ordered his subordinates to let in the Shinokuni gas, while outwardly exclaiming that they can easily be replaced. He then goes as far as personally killing the ones present simply to test out his newly acquired power, revealing his true colors in the process. He is a very prideful person, going as far to say that his work four years ago on the weapon that caused the Punk Hazard incident was not a failure, but instead was a great success, implying a superiority complex. Due to his pride in his own work, he tends to blush when his work is praised, even by the enemy, but turned to indignity when that praise turned towards Vegapunk. He was also shocked to see Smiley not listening to him and eat the candy despite Caesar saying to wait and Caesar said it was alright while Monet noted he was not listening to him. He also does not take kindly to insults, as when Law called him stupid, Caesar lashes out by punching Law's heart. Unlike most Logia users, Caesar keeps his Devil Fruit ability activated all the time and is either completely or partly turned into gas. Caesar has an odd habit of being easily shocked by things that leave him dumbfounded, often doing a comical face-fault, such as when Luffy survived his second Gastanet attack and appeared behind him unharmed. He did so again when Luffy was about to attack him from behind in their second fight together, which seems to be a running gag on his part. Upon Luffy declaring that he does not want to see Caesar's face anymore out of anger, the scientist cried in fear right before he was sent flying by Luffy's Gear Third attack. He also demonstrates tendencies of egomania when Luffy mentioned his Gasu Gasu no Mi had no effect on his immune system due to Magellan's Doku Doku no Mi, both being poisonous Devil Fruits of differentiating class, causing Caesar to become rapidly aggravated from the fact that Luffy compared his Logia powers to that of a "mere" Paramecia user. He was very surprised that his poisons did not affect Luffy due to the latter's immunity to poison given to him from his near-death poisoning by Magellan. Proud of the unexpected power of his Koro gas weapon, he was rather unhappy when the Straw Hat Pirates forced him to counter it to save the poisoned Mink Tribe. He has shown to have maniacal tendencies due to his sedulous research on weapons of mass destruction and his absence of emotion at the time of murdering people or provoking any type of suffering such as giving drugs to the children so they would suffer severe withdrawal and return to his research facility for more "candies" filled with the stimulant, and showing no regret or sorrow for his actions. He is also very sadistic, as he exploited the blind trust of his wounded subordinates to test a newly developed gas and ordered the Yeti Cool Brothers to assassinate Brownbeard when he thought he was no use to him anymore: he further provoked a partially-paralyzed Brownbeard by revealing the truth about the gas explosion four years ago, in order to create an opportunity to have his subordinates shoot him down. He also used the restricted drug NHC10 to maintain his control of the children he kidnapped, knowing that they will be unable to escape due to the agonizing withdrawal symptoms, and that by his own calculations, they will die in five years after he started his experiments with them, which he deems a necessary sacrifice for his science. Law found this aspect of Caesar disgusting. Caesar also seems to enjoy cocktails, as he is often seen holding a cocktail glass. Caesar is also very cowardly when his life is threatened in any way. When he was about to lose to Luffy he attempted to beg the Straw Hat captain to spare him and even make him his subbordinate. He also repeatedly begged Doflamingo to save him and even later begged the Straw Hats to protect him from Big Mom on more than one occasion.
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